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期刊论文 33

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饮用水；长三角；安全保障；微量污染物；新污染物；绿色发展；智慧供水 1

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Decomposition of aqueous chlorinated contaminants by UV irradiation with H

Eunsung KAN,Chang-Il KOH,Kyunghyuk LEE,Joonwun KANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第3期   页码 429-435 doi: 10.1007/s11783-014-0677-6

摘要： In the present study, the decomposition rates of carbon tetrachloride (CCl ) and 2,4-dichlorophenol (2,4-DCP) in water by the ultraviolet (UV) light irradiation alone and H O /UV were experimentally investigated. The detailed experimental studies have been conducted for examining treatment capacities of the two different ultraviolet light sources (low and medium pressure Hg arc) in H O /UV processes. The low or medium UV lamp alone resulted in a 60%–90% decomposition of 2,4-DCP while a slight addition of H O resulted in a drastic enhancement of the 2,4-DCP decomposition rate. The decomposition rate of 2,4-DCP with the medium pressure UV lamp alone was about 3–6 times greater than the low pressure UV lamp alone. In the direct photolysis of aqueous CCl , the medium pressure UV lamp had advantage over the low pressure UV lamp because the molar extinction coefficient of CCl at shorter wavelength (210–220 nm) is about 20 to 50 times higher than that at 254 nm. However, adding H O to the medium pressure UV lamp system rendered a negative oxidation rate because H O acted as a UV absorber being competitive with CCl due to negligible reaction between CCl and OH radicals. The results from the present study indicated significant influence of the photochemical properties of the target contaminants on the photochemical treatment characteristics for designing cost-effective UV-based degradation of toxic contaminants.

关键词： H2O2/ultraviolet (UV) light     advanced oxidation     UV light irradiation     chlorinated contaminants     photochemical treatment characteristics    

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Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper

XU Wenying, GAO Tingyao, ZHOU Rongfeng, MA Lumin

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 207-212 doi: 10.1007/s11783-007-0036-y

摘要： The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltammetry technique. The reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were explored. The relationship between the structure of chlorinated hydrocarbons and their reductive activity were discussed. The experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper electrode. However, chlorinated aromatic hydrocarbons were not easy to reduce at the copper electrode. The results provided a theoretical basis for the catalyzed iron inner electrolysis method.

关键词： electrolysis     chlorinated     relationship     mechanism     voltammetry technique    

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Microbial responses to combined oxidation and catalysis treatment of 1,4-dioxane and co-contaminants

Yu Miao, Nicholas W. Johnson, Kimberly Heck, Sujin Guo, Camilah D. Powell, Thien Phan, Phillip B. Gedalanga, David T. Adamson, Charles J. Newell, Michael S. Wong, Shaily Mahendra

《环境科学与工程前沿（英文）》 2018年 第12卷 第5期 doi: 10.1007/s11783-018-1071-6

摘要：

Groundwater microbial community was altered after catalysis and chemical oxidation.

The coupled treatment train removed 90% 1,4-dioxane regardless of co-contaminants.

Dynamics of microbial populations varied along with different treatment stages.

Many microbial taxa exhibited resilience against oxidative and catalytic treatments.

Metagenomic analysis will be valuable for long-term management of polluted sites.

关键词： Coupled treatments     Chlorinated solvents     Diethylene ether     Biological diversity     Microbial populations     Biomarkers    

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Degradation of chlorinated phenols by nanoscale zero-valent iron

CHENG Rong, WANG Jianlong, ZHANG Weixian

《环境科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 103-108 doi: 10.1007/s11783-008-0009-9

摘要： Chlorophenols (CPs), as important contaminants in groundwater, are toxic and difficult to biodegrade. Recently nanoscale zero-valent iron received a great deal of attention because of its excellent performance in treating recalcitrant compounds. In this study, nanoscale zero-valent iron particles were prepared using chemical reduction, and the reductive transformations of three kinds of chlorinated phenols (2-CP, 3-CP, and 4-CP) by nanoscale zero-valent iron under different conditions were investigated. The transformation process of the CPs was shown to be dechlorination first, then cleavage of the benzene ring. The removal efficiency of the CPs varied as follows: 2-CP > 3-CP > 4-CP. The reactivity of CPs was associated with their energy of lowest unoccupied molecular orbit (). With the increase in initial concentrations of CPs, removal efficiency decreased a little. But the quantities of CPs reduced increased evidently. Temperature had influence on not only the removal efficiency, but also the transformation pathway. At higher temperatures, dechlorination occurred prior to benzene ring cleavage. At lower temperatures, however, the oxidation product was formed more easily.
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Integrated risk assessment framework for transformation products of emerging contaminants: what we know

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1691-3

摘要：

● A better risk assessment can combine the improved non-target analysis method.

关键词： Risk assessment frameworks     Transformation products     Emerging contaminants     High-throughput toxicity screening     Water treatment    

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Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1346-6

摘要：

•Wood and its reassemblies are ideal substrates to develop novel photocatalysts.

关键词： Wood     Nanocatalysts     Photodegradation     Organic contaminants     Composites    

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Bridging science, technology and policy in emerging contaminants control

《环境科学与工程前沿（英文）》 2023年 第17卷 第5期 doi: 10.1007/s11783-023-1665-5

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Fenton process for degradation of selected chlorinated aliphatic hydrocarbons exemplified by trichloroethylene

QIANG Zhimin, BEN Weiwei, HUANG Chin-Pao

《环境科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 397-409 doi: 10.1007/s11783-008-0074-0

摘要： The degradation of selected chlorinated aliphatic hydrocarbons (CAHs) exemplified by trichloroethylene (TCE), 1,1-dichloroethylene (DCE), and chloroform (CF) was investigated with Fenton oxidation process. The results indicate that the degradation rate was primarily affected by the chemical structures of organic contaminants. Hydroxyl radicals (OH) preferred to attack the organic contaminants with an electron-rich structure such as chlorinated alkenes (i.e., TCE and DCE). The dosing mode of Fenton’s reagent, particularly of Fe, significantly affected the degradation efficiency of studied organic compound. A new “time-squared” kinetic model, = exp(-), was developed to express the degradation kinetics of selected CAHs. This model was applicable to TCE and DCE, but inapplicable to CF due to their varied reaction rate constants towards OH. Chloride release was monitored to examine the degree of dechlorination during the oxidation of selected CAHs. TCE was more easily dechlorinated than DCE and CF. Dichloroacetic acid (DCAA) was identified as the major reaction intermediate in the oxidation of TCE, which could be completely removed as the reaction proceeded. No reaction intermediates or byproducts were identified in the oxidation of DCE and CF. Based on the identified intermediate, the reaction mechanism of TCE with Fenton’s reagent was proposed.

关键词： identified     1     1-dichloroethylene     kinetic     Dichloroacetic     Chloride    

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Kinetics and mechanisms of reactions for hydrated electron with chlorinated benzenes in aqueous solution

Haixia YUAN,Huxiang PAN,Jin SHI,Hongjing LI,Wenbo DONG

《环境科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 583-590 doi: 10.1007/s11783-014-0691-8

摘要： The reactions between chlorinated benzenes (CBzs) and hydrated electron ( ) were investigated by the electron beam (EB) and laser flash photolysis (LFP) experiments. Under the EB irradiation, the effects of irradiation dose, initial concentration and the number of Cl atoms on the removal efficiencies were further examined. At 10 kGy, the removal efficiencies of mono-CB, 1,3-diCB, 1,2-diCB and 1,4-diCB were 41.2%, 87.2%, 84.0%, and 84.1%, respectively. While irradiation dose was 50 kGy, the removal efficiencies increased to 47.4%, 95.8%, 95.0%, and 95.2%, respectively. Irradiation of CBzs solutions has shown that the higher the initial concentration, the lower the percentage of CBzs removal. In addition to this, the dechlorination efficiencies of 1,2-dichlorobenzene (1,2-diCB), 1,3-dichlorobenzene (1,3-diCB) and 1,4-dichlorobenzene (1,4-diCB) were much higher than that of chlorobenzene (mono-CB). The kinetics of the reactions was achieved with nanosecond LFP. The rate constants of second-order reaction between with mono-CB, 1,2-diCB, 1,3-diCB and 1,4-diCB were (5.3±0.4) × 10 , (4.76±0.1) × 10 , (1.01±0.1) × 10 and (3.29±0.2) × 10 L·mol ·s , respectively. Density functional theory (DFT) calculations were performed to determine the optical properties of unstable CBzs anion radicals, and the main absorption peaks lied in the range of 300–550 nm. The primary reaction pathway of CBzs with was gradual dechlorination, and the major products were Cl and benzene (CBzs(-Cl )). Furthermore, biphenyl (or chlorobiphenyl) was observed during the LFP, which was probably formed by recombination of benzene radicals.

关键词： chlorinated benzenes     hydrated electron     electron beam     laser flash photolysis    

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Assessing human bioaccessibility of trace contaminants in size-fractionated red mud, derived precipitates

Chunfeng Wang, Yanchen Zhu, Dan Yao, Guanfei Chen, Lianjun Wang

《环境科学与工程前沿（英文）》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0956-0

摘要： The objective of this study was to provide insight into human exposure to trace contaminants bearing red mud, derived precipitates and geopolymeric blocks due to inhalation contact and/or hand-to-mouth ingestion. The in vitro bioaccessibility behavior of trace contaminants was investigated with the PBET (physiologically based extraction test), ALF (artificial lysosomal fluid) and MGS (modified Gamble’ solution) methods. The results showed that total contents of trace contaminants and operation parameters, such as pH and chelating properties of simulated gastrointestinal phases (PBET), played a joint role in controlling the bioaccessibility efficacy for size-fractionated red mud particles. As for airborne particles (<38 µm size fractions), trace contaminants concentrations extracted by MGS was significantly higher than those by ALF. Additionally, higher bioaccessibility (PBET) values of Cu, Pb, Zn, As, V and U were obtained from red mud derived precipitates compared with those of red mud itself. Even though short-term and long-term leaching values of trace contaminants were relatively lower in the prepared geopolymeric blocks, the health risk could be significantly higher due to the more pronounced bioaccessibility characteristics.

关键词： Bioaccessibility     Trace contaminants     Red mud     Precipitates     Geopolymeric blocks.    

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Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1689-x

摘要：

● Application of the MOF-composite membranes in adsorption was discussed.

关键词： Emerging organic contaminants     Metal organic frameworks     Synthesis     Adsorption     Catalysis    

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The influence of chlorinated aromatics' structure on their adsorption characteristics on activated carbon

Pengfei LIN,Yuan ZHANG,Xiaojian ZHANG,Chao CHEN,Yuefeng XIE,Irwin H SUFFET

《环境科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 138-146 doi: 10.1007/s11783-014-0725-2

摘要： This study focused on evaluating the efficiency of powdered activated carbon (PAC) adsorption process and tackling chlorobenzenes and chlorophenols spill in drinking water source. The adsorption kinetics and PAC’s capacities for five chlorobenzenes and three chlorophenols at drinking water contamination levels were studied in order to determine the influence of different functional groups on the adsorption behavior. The results showed that PAC adsorption could be used as an effective emergency drinking water treatment process to remove these compounds. The adsorption kinetics took 30 min to achieve nearly equilibrium and could be described by both pseudo first-order and pseudo second-order models. A mathematic relationship was developed between the pseudo first-order adsorption rate constant, k , and the solutes’ properties including lg , polarizability and molecular weight. The Freundlich isotherm equation could well describe the adsorption equilibrium behaviors of chlorinated aromatics with from 0.920 to 0.999. The H-bond donor/acceptor group, hydrophobicity, solubility and molecular volume were identified as important solute properties that affect the PAC adsorption capacity. These results could assist water professionals in removing chlorinated aromatics during emergency drinking water treatment.

关键词： chlorinated aromatics     adsorption     powdered activated carbon     kinetics     equilibrium    

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Fate and risk assessment of emerging contaminants in reclaimed water production processes

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1392-8

摘要：

• PPCPs had the highest removal efficiency in A2O combined with MBR process (86.8%).

关键词： Trace organic pollution     Antibiotic resistance genes     Reclaimed wastewater     Sludge     Risk assessment     Mass load    

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Application of Fe(VI) in abating contaminants in water: State of art and knowledge gaps

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1373-3

摘要：

• The properties of Fe(VI) were summarized.

关键词： Ferrate     Oxidation     Disinfection     Coagulation     Enhancement    

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Classification of contaminants and treatability evaluation of domestic wastewater

WANG Xiaochang, JIN Pengkang, ZHAO Hongmei, MENG Lingba

《环境科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 57-62 doi: 10.1007/s11783-007-0011-7

摘要： Long-term sampling and analysis were conducted in a domestic wastewater treatment plant for the investigation on the characteristics of the representative contaminants in raw sewage such as SS, COD, BOD5, TP, and TN. All these constituents were classified into dissolved and suspended groups by using a 0.45-µm membrane filter, and the concentration of each constituent in each group was analyzed. As a result, almost 100% of the SS was found to be suspended matter, as well as about 65% of COD, 60% of BOD, 50% of P, and 20% of N. All these could be easily removed by sedimentation or coagulation/sedimentation. A treatability evaluation diagram was proposed for a rational selection of wastewater treatment process in accordance with raw water quality.

关键词： Long-term sampling     selection     accordance     wastewater treatment     coagulation/sedimentation    

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标题 作者 时间 类型 操作

Decomposition of aqueous chlorinated contaminants by UV irradiation with H

Eunsung KAN,Chang-Il KOH,Kyunghyuk LEE,Joonwun KANG

期刊论文

Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper

XU Wenying, GAO Tingyao, ZHOU Rongfeng, MA Lumin

期刊论文

Microbial responses to combined oxidation and catalysis treatment of 1,4-dioxane and co-contaminants

Yu Miao, Nicholas W. Johnson, Kimberly Heck, Sujin Guo, Camilah D. Powell, Thien Phan, Phillip B. Gedalanga, David T. Adamson, Charles J. Newell, Michael S. Wong, Shaily Mahendra

期刊论文

Degradation of chlorinated phenols by nanoscale zero-valent iron

CHENG Rong, WANG Jianlong, ZHANG Weixian

期刊论文

Integrated risk assessment framework for transformation products of emerging contaminants: what we know

期刊论文

Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

期刊论文

Bridging science, technology and policy in emerging contaminants control

期刊论文

Fenton process for degradation of selected chlorinated aliphatic hydrocarbons exemplified by trichloroethylene

QIANG Zhimin, BEN Weiwei, HUANG Chin-Pao

期刊论文

Kinetics and mechanisms of reactions for hydrated electron with chlorinated benzenes in aqueous solution

Haixia YUAN,Huxiang PAN,Jin SHI,Hongjing LI,Wenbo DONG

期刊论文

Assessing human bioaccessibility of trace contaminants in size-fractionated red mud, derived precipitates

Chunfeng Wang, Yanchen Zhu, Dan Yao, Guanfei Chen, Lianjun Wang

期刊论文

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

期刊论文

The influence of chlorinated aromatics' structure on their adsorption characteristics on activated carbon

Pengfei LIN,Yuan ZHANG,Xiaojian ZHANG,Chao CHEN,Yuefeng XIE,Irwin H SUFFET

期刊论文

Fate and risk assessment of emerging contaminants in reclaimed water production processes

期刊论文

Application of Fe(VI) in abating contaminants in water: State of art and knowledge gaps

期刊论文

Classification of contaminants and treatability evaluation of domestic wastewater

WANG Xiaochang, JIN Pengkang, ZHAO Hongmei, MENG Lingba

期刊论文